Form N-Q

UNITED STATES
SECURITIES AND EXCHANGE COMMISSION
Washington, DC 20549

FORM N-Q


QUARTERLY SCHEDULE OF PORTFOLIO HOLDINGS OF REGISTERED MANAGEMENT INVESTMENT COMPANY

Investment Company Act file number         811-5235         

        Nuveen California Municipal Value Fund, Inc.         
(Exact name of registrant as specified in charter)

Nuveen Investments
        333 West Wacker Drive, Chicago, Illinois 60606         

(Address of principal executive offices) (Zip code)


Kevin J. McCarthy Vice President and Secretary
        333 West Wacker Drive, Chicago, Illinois 60606         

(Name and address of agent for service)

Registrant's telephone number, including area code:         312-917-7700        

Date of fiscal year end:            2/28          

Date of reporting period:         5/31/09         

Form N-Q is to be used by management investment companies, other than small business investment companies registered on Form N-5 (§§ 239.24 and 274.5 of this chapter), to file reports with the Commission, not later than 60 days after the close of the first and third fiscal quarters, pursuant to rule 30b1-5 under the Investment Company Act of 1940 (17 CFR 270.30b1-5). The Commission may use the information provided on Form N-Q in its regulatory, disclosure review, inspection, and policymaking roles.

A registrant is required to disclose the information specified by Form N-Q, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-Q unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to the Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. § 3507.

Item 1. Schedule of Investments

    Portfolio of Investments (Unaudited)             
    Nuveen California Municipal Value Fund, Inc. (NCA)             
    May 31, 2009             
Principal        Optional Call         
Amount (000)    Description (1)    Provisions (2)    Ratings (3)    Value 

    Consumer Staples – 2.9% (2.9% of Total Investments)             
$         465    California County Tobacco Securitization Agency, Tobacco Settlement Asset-Backed Bonds, Sonoma    6/15 at 100.00    BBB   $   415,394 
     County Tobacco Securitization Corporation, Series 2005, 4.250%, 6/01/21             
2,000    Golden State Tobacco Securitization Corporation, California, Enhanced Tobacco Settlement    6/17 at 100.00    BBB    1,333,080 
     Asset-Backed Bonds, Series 2007A-1, 5.750%, 6/01/47             
11,010    Golden State Tobacco Securitization Corporation, California, Enhanced Tobacco Settlement    6/22 at 100.00    BBB    4,924,002 
     Asset-Backed Bonds, Series 2007A-2, 0.000%, 6/01/37             

13,475    Total Consumer Staples            6,672,476 

    Education and Civic Organizations – 0.7% (0.7% of Total Investments)             
140    California Educational Facilities Authority, Revenue Bonds, University of Redlands, Series    10/15 at 100.00    A3    125,135 
     2005A, 5.000%, 10/01/35             
    California Educational Facilities Authority, Revenue Bonds, University of the Pacific,             
    Series 2006:             
95     5.000%, 11/01/21    11/15 at 100.00    A2    94,389 
125     5.000%, 11/01/25    11/15 at 100.00    A2    117,264 
1,500    California Statewide Community Development Authority, Certificates of Participation, San Diego    6/09 at 103.00    N/R    1,327,950 
     Space and Science Foundation, Series 1996, 7.500%, 12/01/26             

1,860    Total Education and Civic Organizations            1,664,738 

    Health Care – 9.0% (9.1% of Total Investments)             
310    California Health Facilities Financing Authority, Revenue Bonds, Kaiser Permanante System,    4/16 at 100.00    A+    272,825 
     Series 2006, 5.000%, 4/01/37             
2,040    California Health Facilities Financing Authority, Revenue Bonds, Sutter Health, Series 2008,    11/16 at 100.00    Aa3    1,714,553 
     Trust 3146, 11.375%, 11/15/46 (IF)             
560    California Statewide Communities Development Authority, Revenue Bonds, Adventist Health System    3/15 at 100.00    A    497,011 
     West, Series 2005A, 5.000%, 3/01/35             
3,000    California Statewide Community Development Authority, Insured Health Facility Revenue Bonds,    7/17 at 100.00    AAA    2,986,380 
     Catholic Healthcare West, Series 2008K, 5.500%, 7/01/41 – AGC Insured             
990    California Statewide Community Development Authority, Revenue Bonds, Kaiser Permanante System,    3/16 at 100.00    A+    858,924 
     Series 2006, 5.000%, 3/01/41             
1,460    California Statewide Community Development Authority, Revenue Bonds, Kaiser Permanente System,    8/16 at 100.00    A+    1,365,582 
     Series 2001C, 5.250%, 8/01/31             
2,710    California Statewide Community Development Authority, Revenue Bonds, Sherman Oaks Health    No Opt. Call    A    2,881,977 
     System, Series 1998A, 5.000%, 8/01/22 – AMBAC Insured             
3,390    California Statewide Community Development Authority, Revenue Bonds, Sutter Health, Series    11/15 at 100.00    Aa3    3,049,068 
     2005A, 5.000%, 11/15/43             
1,525    Loma Linda, California, Hospital Revenue Bonds, Loma Linda University Medical Center, Series    12/18 at 100.00    BBB    1,620,907 
     2008A, 8.250%, 12/01/38             
3,000    Santa Clara County Financing Authority, California, Insured Revenue Bonds, El Camino Hospital,    8/17 at 100.00    A1    2,974,650 
     Series 2007A, 5.750%, 2/01/41 – AMBAC Insured             
1,000    Sierra View Local Health Care District, California, Revenue Bonds, Series 2007, 5.250%, 7/01/37    9/17 at 100.00    N/R    856,640 
1,730    West Contra Costa Healthcare District, California, Certificates of Participation, Series 2004,    7/14 at 100.00    A    1,751,383 
     5.375%, 7/01/21 – AMBAC Insured             

21,715    Total Health Care            20,829,900 

    Housing/Multifamily – 1.5% (1.5% of Total Investments)             
2,475    California Statewide Community Development Authority, Multifamily Housing Revenue Bonds,    7/09 at 102.00    N/R    1,894,167 
     Harbor City Lights, Series 1999Y, 6.650%, 7/01/39 (Alternative Minimum Tax)             
445    Riverside County, California, Subordinate Lien Mobile Home Park Revenue Bonds, Bravo Mobile    10/09 at 100.00    N/R    361,260 
     Home Park Project, Series 1999B, 6.500%, 3/20/29             
1,400    San Dimas Housing Authority, California, Mobile Home Park Revenue Bonds, Charter Oak Mobile    7/09 at 101.00    N/R    1,131,158 
     Home Estates Acquisition Project, Series 1998A, 5.700%, 7/01/28             

4,320    Total Housing/Multifamily            3,386,585 

    Housing/Single Family – 2.3% (2.3% of Total Investments)             
315    California Housing Finance Agency, Home Mortgage Revenue Bonds, Series 2006H, 5.750%,    2/16 at 100.00    Aa2    315,765 
     8/01/30 – FGIC Insured (Alternative Minimum Tax)             
4,390    California Housing Finance Agency, Home Mortgage Revenue Bonds, Series 2007M, 4.700%, 8/01/36    2/16 at 100.00    Aa2    3,227,616 
     (Alternative Minimum Tax)             
2,125    California State Department of Veteran Affairs, Home Purchase Revenue Bonds, Series 2007,    12/16 at 100.00    Aa2    1,778,009 
     5.000%, 12/01/42 (Alternative Minimum Tax)             

6,830    Total Housing/Single Family            5,321,390 

    Industrials – 0.4% (0.4% of Total Investments)             
1,000    California Pollution Control Financing Authority, Solid Waste Disposal Revenue Bonds, Waste    1/16 at 102.00    BBB    908,260 
     Management Inc., Series 2002A, 5.000%, 1/01/22 (Alternative Minimum Tax)             

    Long-Term Care – 5.8% (5.9% of Total Investments)             
    ABAG Finance Authority for Non-Profit Corporations, California, Cal-Mortgage Revenue Bonds,             
    Elder Care Alliance of Union City, Series 2004:             
1,850     5.400%, 8/15/24    8/14 at 100.00    A    1,842,249 
2,130     5.600%, 8/15/34    8/14 at 100.00    A    2,033,064 
2,505    ABAG Finance Authority for Non-Profit Corporations, California, Certificates of Participation,    10/09 at 100.00    BBB–    2,250,166 
     American Baptist Homes of the West, Series 1997A, 5.750%, 10/01/17             
4,000    ABAG Finance Authority for Non-Profit Corporations, California, Health Facility Revenue Bonds,    8/18 at 100.00    A    3,882,800 
     The Institute on Aging, Series 2008A, 5.650%, 8/15/38             
2,230    California Statewide Community Development Authority, Certificates of Participation, Internext    10/09 at 101.00    BBB    2,064,668 
     Group, Series 1999, 5.375%, 4/01/17             
1,500    Riverside County Public Financing Authority, California, Certificates of Participation, Air    11/09 at 101.00    BBB–    1,370,580 
     Force Village West, Series 1999, 5.750%, 5/15/19             

14,215    Total Long-Term Care            13,443,527 

    Tax Obligation/General – 1.9% (1.9% of Total Investments)             
500    California, General Obligation Bonds, Series 2004, 5.000%, 2/01/20    2/14 at 100.00    A    507,915 
1,500    Los Angeles Unified School District, California, General Obligation Bonds, Series 2006F,    7/16 at 100.00    AA–    1,530,420 
     5.000%, 7/01/24 – FGIC Insured             
2,000    Puerto Rico, General Obligation and Public Improvement Bonds, Series 2001A, 5.500%, 7/01/20 –    No Opt. Call    AA–    2,000,720 
     MBIA Insured             
270    Roseville Joint Union High School District, Placer County, California, General Obligation    8/15 at 100.00    AA–    274,280 
     Bonds, Series 2006B, 5.000%, 8/01/27 – FGIC Insured             

4,270    Total Tax Obligation/General            4,313,335 

    Tax Obligation/Limited – 29.5% (29.8% of Total Investments)             
1,000    Artesia Redevelopment Agency, California, Tax Allocation Revenue Bonds, Artesia Redevelopment    6/15 at 100.00    BBB    825,330 
     Project Area, Series 2007, 5.375%, 6/01/27             
    Bell Community Redevelopment Agency, California, Tax Allocation Bonds, Bell Project Area,             
    Series 2003:             
3,000     5.500%, 10/01/23 – RAAI Insured    10/13 at 100.00    BBB–    2,867,940 
1,000     5.625%, 10/01/33 – RAAI Insured    10/13 at 100.00    BBB–    903,810 
2,400    Calexico Community Redevelopment Agency, California, Tax Allocation Bonds, Merged Central    8/13 at 102.00    A    2,153,784 
     Business and Residential District Project, Series 2003C, 5.000%, 8/01/28 – AMBAC Insured             
340    Capistrano Unified School District, Orange County, California, Special Tax Bonds, Community    9/15 at 100.00    AA–    317,903 
     Facilities District, Series 2005, 5.000%, 9/01/24 – FGIC Insured             
1,005    Chino Redevelopment Agency, California, Merged Chino Redevelopment Project Area Tax Allocation    9/16 at 101.00    A    819,869 
     Bonds, Series 2006, 5.000%, 9/01/38 – AMBAC Insured             
    Golden State Tobacco Securitization Corporation, California, Tobacco Settlement Asset-Backed             
    Revenue Bonds, Series 2005A:             
20,110     5.000%, 6/01/35 – FGIC Insured    6/15 at 100.00    A–    17,478,606 
2,345     5.000%, 6/01/38 – FGIC Insured    6/15 at 100.00    A–    2,013,089 
    Irvine, California, Unified School District, Community Facilities District Special Tax Bonds,             
    Series 2006A:             
160     5.000%, 9/01/26    9/16 at 100.00    N/R    140,818 
375     5.125%, 9/01/36    9/16 at 100.00    N/R    308,483 
2,500    Kern County Board of Education, California, Certificates of Participation, Series 2006A,    6/16 at 100.00    AA–    2,353,750 
     5.000%, 6/01/31 – MBIA Insured             
615    Los Angeles Community Redevelopment Agency, California, Lease Revenue Bonds, Manchester Social    9/15 at 100.00    A2    553,266 
     Services Project, Series 2005, 5.000%, 9/01/37 – AMBAC Insured             
2,750    Los Angeles County Schools, California, Certificates of Participation, Pooled Financing    9/13 at 100.00    AAA    2,768,645 
     Program, Regionalized Business Services Corporation, Series 2003A, 5.000%, 9/01/28 –             
     FSA Insured             
3,665    Milpitas, California, Local Improvement District 20 Limited Obligation Bonds, Series 1998A,    9/09 at 103.00    N/R    3,580,155 
     5.650%, 9/02/13             
    Modesto Schools Infrastructure Financing Agency, Stanislaus County, California, Special Tax             
    Revenue Bonds, Series 2004:             
1,045     5.250%, 9/01/22 – AMBAC Insured    9/14 at 100.00    A    976,929 
1,145     5.250%, 9/01/23 – AMBAC Insured    9/14 at 100.00    A    1,054,419 
1,255     5.250%, 9/01/24 – AMBAC Insured    9/14 at 100.00    A    1,146,430 
420    Oakland Redevelopment Agency, California, Subordinate Lien Tax Allocation Bonds, Central    3/13 at 100.00    AA–    421,088 
     District Redevelopment Project, Series 2003, 5.500%, 9/01/18 – FGIC Insured             
8,000    Palmdale Elementary School District, Los Angeles County, California, Special Tax Bonds,    8/09 at 101.00    AAA    8,025,279 
     Community Facilities District 90-1, Series 1999, 5.800%, 8/01/29 – FSA Insured             
290    Rialto Redevelopment Agency, California, Tax Allocation Bonds, Merged Project Area, Series    9/15 at 100.00    A–    249,487 
     2005A, 5.000%, 9/01/35 – SYNCORA GTY Insured             
5,000    Riverside County Redevelopment Agency, California, Tax Allocation Housing Bonds, Series 2004A,    10/14 at 100.00    A–    4,250,350 
     5.000%, 10/01/37 – SYNCORA GTY Insured             
360    Roseville, California, Certificates of Participation, Public Facilities, Series 2003A, 5.000%,    8/13 at 100.00    AA–    331,787 
     8/01/25 – AMBAC Insured             
3,130    San Francisco Redevelopment Agency, California, Lease Revenue Bonds, Moscone Convention    7/11 at 102.00    AA–    3,221,490 
     Center, Series 2004, 5.250%, 7/01/23 – AMBAC Insured             
2,750    San Jose Financing Authority, California, Lease Revenue Refunding Bonds, Convention Center    9/11 at 100.00    AA+    2,830,328 
     Project, Series 2001F, 5.000%, 9/01/20 – MBIA Insured             
625    San Mateo Union High School District, San Mateo County, California, Certificates of    12/17 at 100.00    A    561,800 
     Participation, Phase 1, Series 2007A, 5.000%, 12/15/30 – AMBAC Insured             
740    Shafter Joint Powers Financing Authority, California, Lease Revenue Bonds, Community    7/09 at 100.00    A–    741,806 
     Correctional Facility Acquisition Project, Series 1997A, 5.950%, 1/01/11             
1,000    Simi Valley, California, Certificates of Participation, Series 2004, 5.000%, 9/01/24 –    9/14 at 100.00    A    1,000,840 
     AMBAC Insured             
1,500    Tehachapi Redevelopment Agency, California, Tax Allocation Bonds, Series 2007, 5.250%,    No Opt. Call    BBB    1,110,705 
     12/01/37 – RAAI Insured             
1,925    Travis Unified School District, Solano County, California, Certificates of Participation,    9/16 at 100.00    N/R    1,733,058 
     Series 2006, 5.000%, 9/01/26 – FGIC Insured             
2,500    Ventura County Superintendent of Schools, California, Certificates Participation, Series 2003,    12/11 at 100.00    AA–    2,504,075 
     5.000%, 12/01/27 – AMBAC Insured             
1,185    Vista Joint Powers Financing Authority, California, Special Tax Lease Revenue Refunding Bonds,    9/09 at 100.00    N/R    1,037,325 
     Community Facilities District 90-2, Series 1997A, 5.875%, 9/01/20             

74,135    Total Tax Obligation/Limited            68,282,644 

    Transportation – 4.1% (4.2% of Total Investments)             
2,500    Bay Area Toll Authority, California, Revenue Bonds, San Francisco Bay Area Toll Bridge, Series    4/16 at 100.00    AA    2,507,025 
     2006, 5.000%, 4/01/31 (UB)             
5,500    Foothill/Eastern Transportation Corridor Agency, California, Toll Road Revenue Refunding    1/14 at 101.00    BBB–    4,588,925 
     Bonds, Series 1999, 0.000%, 1/15/27             
1,250    Fresno, California, Airport Revenue Bonds, Series 2000A, 5.500%, 7/01/30 – FSA Insured    7/10 at 101.00    AAA    1,251,150 
220    Palm Springs Financing Authority, California, Palm Springs International Airport Revenue    7/14 at 102.00    N/R    155,923 
     Bonds, Series 2006, 5.550%, 7/01/28 (Alternative Minimum Tax)             
1,245    San Francisco Airports Commission, California, Revenue Bonds, San Francisco International    5/11 at 100.00    AA    1,082,963 
     Airport, Second Series 1999, Issue 23A, 5.000%, 5/01/30 – FGIC Insured (Alternative             
     Minimum Tax)             

10,715    Total Transportation            9,585,986 

    U.S. Guaranteed – 26.3% (26.5% of Total Investments) (4)             
    Burbank Redevelopment Agency, California, Tax Allocation Bonds, Golden State Redevelopment             
    Project, Series 2003:             
1,700     5.625%, 12/01/28 (Pre-refunded 12/01/13) – FGIC Insured    12/13 at 100.00    N/R (4)    1,968,855 
5,010     5.750%, 12/01/33 (Pre-refunded 12/01/13) – FGIC Insured    12/13 at 100.00    N/R (4)    5,829,235 
2,400    California County Tobacco Securitization Agency, Tobacco Settlement Asset-Backed Bonds, Sonoma    6/12 at 100.00    N/R (4)    2,584,536 
     County Tobacco Funding Corporation, Series 2002B, 5.500%, 6/01/30 (Pre-refunded 6/01/12)             
3,300    California Department of Water Resources, Power Supply Revenue Bonds, Series 2002A, 5.125%,    5/12 at 101.00    Aaa    3,689,994 
     5/01/18 (Pre-refunded 5/01/12)             
3,115    California Educational Facilities Authority, Revenue Bonds, Pooled College and University    6/10 at 101.00    Baa3 (4)    3,314,111 
     Projects, Series 2000C, 6.750%, 6/01/30 (ETM)             
2,845    California, General Obligation Bonds, Series 2004, 5.250%, 4/01/34 (Pre-refunded 4/01/14)    4/14 at 100.00    AAA    3,299,261 
3,260    California, Various Purpose General Obligation Bonds, Series 2000, 5.750%, 3/01/27    3/10 at 101.00    AAA    3,414,068 
     (Pre-refunded 3/01/10) – MBIA Insured             
2,065    Contra Costa County, California, GNMA Mortgage-Backed Securities Program Home Mortgage Revenue    No Opt. Call    AAA    2,834,274 
     Bonds, Series 1988, 8.250%, 6/01/21 (Alternative Minimum Tax) (ETM)             
2,105    Golden State Tobacco Securitization Corporation, California, Tobacco Settlement Asset-Backed    6/13 at 100.00    AAA    2,303,544 
     Bonds, Series 2003A-1, 6.250%, 6/01/33 (Pre-refunded 6/01/13)             
1,330    Los Angeles Community Redevelopment Agency, California, Tax Allocation Refunding Bonds,    7/09 at 100.00    BBB (4)    1,336,756 
     Central Business District Redevelopment Project, Series 1987G, 6.750%, 7/01/10 (ETM)             
5,000    Orange County Sanitation District, California, Certificates of Participation, Series 2003,    8/13 at 100.00    AAA    5,753,700 
     5.250%, 2/01/27 (Pre-refunded 8/01/13) – FGIC Insured             
8,565    Palmdale, California, GNMA Mortgage-Backed Securities Program Single Family Mortgage Revenue    No Opt. Call    AAA    6,566,699 
     Bonds, Series 1988A, 0.000%, 3/01/17 (ETM)             
3,300    Puerto Rico Highway and Transportation Authority, Highway Revenue Bonds, Series 2002D, 5.375%,    7/12 at 100.00    AAA    3,657,588 
     7/01/36 (Pre-refunded 7/01/12)             
20,415    San Bernardino County, California, GNMA Mortgage-Backed Securities Program Single Family Home    No Opt. Call    AAA    10,896,505 
     Mortgage Revenue Bonds, Series 1988A, 0.000%, 9/01/21 (Alternative Minimum Tax) (ETM)             
3,000    Virgin Islands Public Finance Authority, Gross Receipts Taxes Loan Note, Series 1999A, 6.500%,    10/10 at 101.00    BBB+ (4)    3,263,070 
     10/01/24 (Pre-refunded 10/01/10)             

67,410    Total U.S. Guaranteed            60,712,196 

    Utilities – 6.9% (6.9% of Total Investments)             
2,445    California Statewide Community Development Authority, Certificates of Participation Refunding,    6/09 at 100.00    N/R    1,942,724 
     Rio Bravo Fresno Project, Series 1999A, 6.500%, 12/01/18 (5)             
1,800    Long Beach Bond Finance Authority, California, Natural Gas Purchase Revenue Bonds, Series    No Opt. Call    A    1,537,038 
     2007A, 5.500%, 11/15/37             
21,500    Merced Irrigation District, California, Certificates of Participation, Water and Hydroelectric    9/16 at 64.56    A    8,402,844 
     System Projects, Series 2008A, 0.000%, 9/01/23             
605    Merced Irrigation District, California, Electric System Revenue Bonds, Series 2005, 5.125%,    9/15 at 100.00    BBB–    484,853 
     9/01/31 – SYNCORA GTY Insured             
3,470    Puerto Rico Industrial, Tourist, Educational, Medical and Environmental Control Facilities    6/10 at 101.00    Baa3    3,474,546 
     Financing Authority, Co-Generation Facility Revenue Bonds, Series 2000A, 6.625%, 6/01/26             
     (Alternative Minimum Tax)             

29,820    Total Utilities            15,842,005 

    Water and Sewer – 7.9% (7.9% of Total Investments)             
1,480    California Department of Water Resources, Water System Revenue Bonds, Central Valley Project,    6/15 at 100.00    AAA    1,581,528 
     Series 2005AD, 5.000%, 12/01/22 – FSA Insured             
1,500    Castaic Lake Water Agency, California, Certificates of Participation, Series 2006C, 5.000%,    8/16 at 100.00    AA–    1,469,325 
     8/01/36 – MBIA Insured             
410    Healdsburg Public Financing Authority, California, Wastewater Revenue Bonds, Series 2006,    4/16 at 100.00    AA–    382,473 
     5.000%, 4/01/36 – MBIA Insured             
500    Los Angeles County Sanitation Districts Financing Authority, California, Senior Revenue Bonds,    10/13 at 100.00    AAA    515,490 
     Capital Projects, Series 2003A, 5.000%, 10/01/23 – FSA Insured             
5,000    Los Angeles Department of Water and Power, California, Waterworks Revenue Bonds, Series    7/17 at 100.00    AA    4,829,800 
     2007A-2, 5.000%, 7/01/44 – AMBAC Insured             
    Madera Irrigation District, California, Water Revenue Refunding Bonds, Series 2008:             
1,850     5.500%, 1/01/33    1/18 at 100.00    A–    1,851,147 
3,000     5.500%, 1/01/38    1/18 at 100.00    A–    2,974,200 
1,580    San Diego County Water Authority, California, Water Revenue Refunding Certificates of    5/12 at 101.00    AA+    1,607,492 
     Participation, Series 2002A, 5.000%, 5/01/26 – MBIA Insured             
3,500    Woodbridge Irrigation District, California, Certificates of Participation, Water Systems    7/13 at 100.00    A+    2,993,480 
     Project, Series 2003, 5.625%, 7/01/43             

18,820    Total Water and Sewer            18,204,935 

$      268,585    Total Investments (cost $230,891,901) – 99.2%            229,167,977 


    Floating Rate Obligations – (0.5)%            (1,250,000)

    Other Assets Less Liabilities – 1.3%            3,175,169 

    Net Assets Applicable to Common Shares – 100%           $   231,093,146 



Fair Value Measurements

During the current fiscal period, the Fund adopted the provisions of Statement of Financial Accounting Standards No. 157 (SFAS No. 157) “Fair Value Measurements.” SFAS No. 157 defines fair value, establishes a framework for measuring fair value in generally accepted accounting principles and expands disclosure about fair value measurements. In determining the value of the Fund’s investments various inputs are used. These inputs are summarized in the three broad levels listed below:

Level 1 – Quoted prices in active markets for identical securities.

Level 2 – Other significant observable inputs (including quoted prices for similar securities, interest rates, prepayment speeds, credit risk, etc.).

Level 3 – Significant unobservable inputs (including management’s assumptions in determining the fair value of investments).

The inputs or methodology used for valuing securities are not an indication of the risk associated with investing in those securities. The following is a summary of the Fund’s fair value measurements as of May 31, 2009:

    Level 1    Level 2    Level 3    Total 

Investments    $ —    $229,167,977    $ —    $229,167,977 


Income Tax Information

The following information is presented on an income tax basis. Differences between amounts for financial statement and federal income tax purposes are primarily due to timing differences in recognizing taxable market discount, timing differences in recognizing certain gains and losses on investment transactions and the treatment of investments in inverse floating rate transactions subject to Statement of Financial Accounting Standards No. 140 (SFAS No. 140), if any. To the extent that differences arise that are permanent in nature, such amounts are reclassified within the capital accounts on the Statement of Assets and Liabilities presented in the annual report, based on their federal tax basis treatment; temporary differences do not require reclassification. Temporary and permanent differences do not impact the net asset value of the Fund.

At May 31, 2009, the cost of investments was $229,689,066.

Gross unrealized appreciation and gross unrealized depreciation of investments at May 31, 2009, were as follows:


Gross unrealized:     
  Appreciation    $ 12,911,068 
  Depreciation    (14,682,169)

Net unrealized appreciation (depreciation) of investments    $  (1,771,101)


(1)    All percentages shown in the Portfolio of Investments are based on net assets applicable to Common 
    Shares unless otherwise noted. 
(2)    Optional Call Provisions: Dates (month and year) and prices of the earliest optional call or redemption. There 
    may be other call provisions at varying prices at later dates. Certain mortgage-backed securities may be 
    subject to periodic principal paydowns. 
(3)    Ratings: Using the higher of Standard & Poor’s Group (“Standard & Poor’s”) or Moody’s Investor Service, Inc. 
    (“Moody’s”) rating. Ratings below BBB by Standard & Poor’s or Baa by Moody’s are considered to be below 
    investment grade. 
(4)    Backed by an escrow or trust containing sufficient U.S. Government or U.S. Government agency securities 
    which ensure the timely payment of principal and interest. Such investments are normally considered to be 
    equivalent to AAA rated securities. 
(5)    This debt has been restructured to accommodate capital maintenance at the facility. Major highlights of 
    the debt restructuring include the following: (1) the principal balance outstanding on and after 
    December 1, 2007, shall accrue interest at a rate of 6.500% per annum commencing December 1, 2007; 
    (2) the interest shall accrue but not be payable on June 1, 2008 or December 1, 2008, but shall instead be 
    deferred and paid by the end of calendar year 2011; (3) no principal component shall be pre-payable from 
    the Minimum Sinking Fund Account during calendar years 2008 and 2009 but such pre-payments shall 
    recommence beginning in calendar year 2010 according to a revised schedule. Management believes that 
    the restructuring is in the best interest of Fund shareholders and that it is more-likely-than-not that the 
    borrower will fulfill its obligation. Consequently, the Fund continues to accrue interest on this obligation. 
N/R    Not rated. 
(ETM)    Escrowed to maturity. 
(IF)    Inverse floating rate investment. 
(UB)    Underlying bond of an inverse floating rate trust reflected as a financing transaction pursuant to the 
    provisions of SFAS No. 140. 


Item 2. Controls and Procedures.

  1. The registrant's principal executive and principal financial officers, or persons performing similar functions, have concluded that the registrant's disclosure controls and procedures (as defined in Rule 30a-3(c) under the Investment Company Act of 1940, as amended (the "1940 Act") (17 CFR 270.30a-3(c))) are effective, as of a date within 90 days of the filing date of this report that includes the disclosure required by this paragraph, based on their evaluation of the controls and procedures required by Rule 30a-3(b) under the 1940 Act (17 CFR 270.30a-3(b)) and Rule 13a-15(b) or 15d-15(b) under the Securities Exchange Act of 1934 (17 CFR 240.13a-15(b) or 240.15d-15(b)).
  2. There were no changes in the registrant's internal control over financial reporting (as defined in Rule 30a-3(d) under the 1940 Act (17 CFR 270.30a-3(d)) that occurred during the registrant's last fiscal quarter that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting.

Item 3. Exhibits.

File as exhibits as part of this Form a separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2(a) under the 1940 Act (17 CFR 270.30a-2(a)), exactly as set forth below: See EX-99 CERT attached hereto.


SIGNATURES

Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized.

(Registrant)         Nuveen California Municipal Value Fund, Inc.         

By (Signature and Title)          /s/ Kevin J. McCarthy                    
                                                  Kevin J. McCarthy
                                                  Vice President and Secretary

Date         July 30, 2009        

Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated.

By (Signature and Title)         /s/ Gifford R. Zimmerman                    
                                                 Gifford R. Zimmerman
                                                 Chief Administrative Officer (principal executive officer) 

Date         July 30, 2009        

By (Signature and Title)         /s/ Stephen D. Foy                              
                                                 Stephen D. Foy
                                                 Vice President and Controller (principal financial officer) 

Date        July 30, 2009